Yakar Zemach

and 6 more

Marine continental shelf sediments with high deposition rates may provide useful archives of rapid geomagnetic secular variation as long as the primary magnetization is not altered substantially by diagenesis. To quantify the effects of sulfate (SO42-) reduction, which is a dominant early diagenetic processes in such sediments, on paleomagnetic recording, we analyzed four ~6-m long sediment cores from the Mediterranean shelf. Two cores did not reach the methanogenic zone and are characterized by continuous organoclastic sulfate reduction (OSR), while the other two have a distinctive shallow sulfate-methane transition zone (SMTZ). Depth-age models based on 28 radiocarbon ages show that deposition was mostly non-synchronous, suggesting that different parts of the shelf stopped accumulating sediments at different times during the Holocene. The upper sediment column in all cores is dominated by detrital titanomagnetite and biogenic magnetite. OSR-affected sediments record continuous dissolution of the (titano)magnetites, resulting in a steady decrease in magnetic susceptibility and remanent magnetic properties. For cores that reach the methanogenic zone, similar behavior is observed at or above the STMZ, but the magnetic properties stabilize at greater depths. Paleomagnetic directions in these sediments are more coherent, with better agreement with geomagnetic models than sediments affected by OSR. We suggest that methane-rich sediments with a shallow SMTZ and high sedimentation rates can better preserve primary paleomagnetic signals than OSR-dominated sediments due to a lack of dissolved sulfide in the main methanogenic zone, and that a susceptibility decline with depth should be a warning sign for paleomagnetic studies.

Inbar Vaknin

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Pockmarks are morphological depressions commonly observed in ocean and lake floors. Pockmarks form by fluid (typically gas) seepage thorough a sealing sedimentary layer, deforming and breaching the layer. The seepage-induced sediment deformation mechanisms, and their links to the resulting pockmarks morphology, are not well understood. To bridge this gap, we conduct laboratory experiments in which gas seeps through a granular (sand) reservoir, overlaid by a (clay) seal, both submerged under water. We find that gas rises through the reservoir and accumulates at the seal base. Once sufficient gas over-pressure is achieved, gas deforms the seal, and finally escapes via either: (i) doming of the seal followed by dome breaching via fracturing; (ii) brittle faulting, delineating a plug. The gas lifts the plug and seeps through the bounding faults; or (iii) plastic deformation by bubbles ascending through the seal. The preferred mechanism is found to depend on the seal thickness and stiffness: in stiff seals, a transition from doming and fracturing to brittle faulting occurs as the thickness increases, whereas bubbles rise is preferred in the most compliant, thickest seals. Seepage can also occur by mixed modes, such as bubbles rising in faults. Repeated seepage events suspend the sediment at the surface and create pockmarks. We present a quantitative analysis that explains the tendency for the various modes of deformation observed experimentally. Finally, we connect simple theoretical arguments with field observations, highlighting similarities and differences that bound the applicability of laboratory experiments to natural pockmarks.