We deformed samples with varied proportions of olivine and orthopyroxene in a deformation-DIA apparatus to test the applicability of subgrain-size piezometry to polymineralic rocks. We measured the stress within each phase in situ via X-ray diffraction during deformation at a synchrotron beamline. Subgrain-size piezometry was subsequently applied to the recovered samples to estimate the stress that each phase supported during deformation. For olivine, the final in-situ stresses are consistent with the stresses estimated via subgrain-size piezometry, both in monomineralic and polymineralic samples, despite non-steady state conditions. However, stress estimates from subgrain-size piezometry do not reliably record the in-situ stress in samples with grain sizes that are too small for extensive subgrain-boundary formation. For orthopyroxene, subgrain boundaries are typically sparse due to the low strains attained by orthopyroxene in olivine-orthopyroxene mixtures. Where sufficient substructure does exist, our data supports the use of the subgrain-size piezometer on orthopyroxene. These results do, however, suggest that care should be taken when applying subgrain-size piezometry to strong minerals that may have experienced little strain. Stresses estimated by X-ray diffraction also offer insight into stress partitioning between phases. In mixtures deformed at mean stresses > 5 GPa, orthopyroxene supports stresses greater than those supported by olivine. This stress partitioning is consistent with established theory that predicts a slightly higher stress within a ‘strong’ phase contained in a material consisting of interconnected weak layers. Overall, these results demonstrate that subgrain-size piezometry is a valuable tool for quantifying the stress state of polymineralic rocks.

• Nanoindentation experiments on a high-angle grain boundary (60 • misorientation) in a pure forsterite bicrystal reveal that the interface acts as a source of dislocations. • Nanoindentation experiments on a high-angle grain boundary (60 • misorientation) in a pure forsterite bicrystal reveal that the interface acts as an obstacle to incoming dislocations, leading to pileups of dislocations. • Nanoindentation experiments on a subgrain boundary (13 • misorientation) in a pure forsterite bicrystal do not detect the impact of the interface on dislocations.

Transient creep occurs during geodynamic processes that impose stress changes on rocks at high temperatures. The transient is manifested as evolution in the viscosity of the rocks until steady-state flow is achieved. Although several phenomenological models of transient creep in rocks have been proposed, the dominant microphysical processes that control such behavior remain poorly constrained. To identify the intragranular processes that contribute to transient creep of olivine, we performed stress-reduction tests on single crystals of olivine at temperatures of 1250–1300°C. In these experiments, samples undergo time-dependent reverse strain after the stress reduction. The magnitude of reverse strain is ~10-3 and increases with increasing magnitude of the stress reduction. High-angular resolution electron backscatter diffraction analyses of deformed material reveal lattice curvature and heterogeneous stresses associated with the dominant slip system. The mechanical and microstructural data are consistent with transient creep of the single crystals arising from accumulation and release of backstresses among dislocations. These results allow the dislocation-glide component of creep at high temperatures to be isolated, and we use these data to calibrate a flow law for olivine to describe the glide component of creep over a wide temperature range. We argue that this flow law can be used to estimate both transient creep and steady-state viscosities of olivine, with the transient evolution controlled by the evolution of the backstress. This model is able to predict variability in the style of transient (normal versus inverse) and the load-relaxation response observed in previous work.

The spatial separation of macroscopic rheological behaviours has led to independent conceptual treatments of frictional failure, often referred to as brittle, and viscous deformation. Detailed microstructural investigations of naturally deformed carbonate rocks indicate that both, frictional failure, and viscous mechanisms might operate during seismic deformation of carbonates. Here, we investigate the deformation mechanisms that were active in two carbonate fault zones in Greece by performing detailed slip-system analyses on data from automated crystal-orientation mapping transmission electron microscopy and electron backscatter diffraction. We combine the slip system analyses with interpretations of nanostructures and predictions from deformation mechanism maps for calcite. The nanometric grains at the principal slip surface should deform by diffusion creep but the activation of the (0001)<-12-10> slip system is evidence for a contribution of crystal plasticity. A similar crystallographic preferred orientation appears in the cataclastic parts of the fault rocks despite exhibiting a larger grain size and a different fractal dimension, compared to the principal slip surface. The cataclastic region exhibits microstructures consistent with activation of the (0001)<-12-10> and {10-14}<-2021> slip systems. Post-deformational, static recrystallisation and annealing produces an equilibrium microstructure with triple junctions and equant grain size. We propose that repeated introduction of plastic strain and recrystallisation reduces the grain size and offers a mechanism to form a cohesive nanogranular material. This formation mechanism leads to a grain-boundary strengthening effect resulting in slip delocalisation which is observed over six orders of magnitude (μm–m) and is expressed by multiple faults planes, suggesting cyclic repetition of deformation and annealing.

Large earthquakes transfer stress from the shallow lithosphere to the underlying viscoelastic lower crust and upper mantle, inducing transient creep during the postseismic interval. Recent experiments on olivine have provided a new rheological model for this transient creep based on accumulation and release of back stresses among dislocations. Here, we test whether natural rocks preserve dislocation-induced stress heterogeneity consistent with the back-stress hypothesis by mapping olivine from the palaeosubduction interface of the Oman-UAE ophiolite with high-angular resolution electron backscatter diffraction. The olivine preserves heterogeneous residual stresses that vary in magnitude by several hundred megapascals over length scales of a few micrometres. Large stresses are commonly spatially associated with elevated densities of geometrically necessary dislocations within subgrain interiors. These spatial relationships, along with characteristic probability distributions of the stresses, confirm that the stress heterogeneity is generated by the dislocations and records their long-range elastic interactions. Images of dislocations decorated by oxidation display bands of high and low dislocation density, suggesting that dislocation interactions contributed to organisation of the substructure. These results support the applicability of the back-stress model of transient creep to deformation in the mantle portion of plate-boundary shear zones. The model predicts that rapid stress changes, such as those imposed by large earthquakes, can induce order-of-magnitude changes in viscosity that depend nonlinearly on the stress change, consistent with inferences of mantle rheology from geodetic observations.