We assess the effective radiative forcing due to ozone-depleting substances using models participating in the Aerosols and Chemistry Model Intercomparison Project (AerChemMIP). A large inter-model spread in this globally averaged quantity necessitates an “emergent constraint” approach whereby we link the radiative forcing to the amount of ozone depletion simulated during 1979-2000, excluding two volcanically perturbed periods. During this period ozone-depleting substances were increasing, and several merged satellite-based climatologies document the ensuing decline of total-column ozone. We use these analyses to come up with effective radiative forcing magnitudes. For all of these satellite climatologies we find an effective radiative forcing outside or on the edge of the previously published “likely” range given by the 5th Assessment Report of IPCC, implying an offsetting effect of ozone depletion and/or other atmospheric feedbacks of -0.4 to -0.25 Wm-2, which is in absolute terms is larger than the previous best estimate of -0.15 Wm-2.

We quantify the impacts of halogenated ozone-depleting substances (ODSs), methane, N2O, CO2, and short-lived ozone precursors on total and partial ozone column changes between 1850 and 2014 using CMIP6 Aerosol and Chemistry Model Intercomparison Project (AerChemMIP) simulations. We find that whilst substantial ODS-induced ozone loss dominates the stratospheric ozone changes since the 1970s, the increases in short-lived ozone precursors and methane lead to increases in tropospheric ozone since the 1950s that make increasingly important contributions to total column ozone (TCO) changes. Our results show that methane impacts stratospheric ozone changes through its reaction with atomic chlorine leading to ozone increases, but this impact will decrease with declining ODSs. The N2O increases mainly impact ozone through NOx-induced ozone destruction in the stratosphere, having an overall small negative impact on TCO. CO2 increases lead to increased global stratospheric ozone due to stratospheric cooling. However, importantly CO2 increases cause TCO to decrease in the tropics. Large interannual variability obscures the responses of stratospheric ozone to N2O and CO2 changes. Substantial inter-model differences originate in the models’ representations of ODS-induced ozone depletion. We find that, although the tropospheric ozone trend is driven by the increase in its precursors, the stratospheric changes significantly impact the upper tropospheric ozone trend through modified stratospheric circulation and stratospheric ozone depletion. The speed-up of stratospheric overturning (i.e. decreasing age of air) is driven mainly by ODS and CO2; increases. Changes in methane and ozone precursors also modulate the cross-tropopause ozone flux.