The January 2022 eruption of Hunga Tonga-Hunga Ha’apai (HT-HH) caused the largest enhancement in stratospheric aerosol loading in decades and produced an unprecedented enhancement in stratospheric water vapor, which led to strong stratospheric cooling that in turn induced changes in the large-scale circulation. Here we use satellite measurements of gas-phase constituents together with aerosol extinction to investigate the extent to which the thick aerosol, excess moisture, and strong cooling enabled heterogeneous chemical processing. In the southern tropics, unambiguous signatures of substantial chlorine and nitrogen repartitioning appear over a broad vertical domain almost immediately after the eruption, with depletion of N2O5, NOx, and HCl accompanied by enhancement of HNO3, ClO, and ClONO2. After initially rising steeply, HNO3 and ClO plateau, maintaining fairly constant abundances for several months. These patterns are consistent with the saturation of N2O5 hydrolysis, suggesting that this reaction is the primary mechanism for the observed composition changes. The southern midlatitudes and subtropics show similar but weaker enhancements in ClO and ClONO2. In those regions, however, effects of anomalous transport dominate the evolution of HNO3 and HCl, obscuring the signs of heterogeneous processing. Perturbations in chlorine species are considerably weaker than those measured in the southern midlatitude stratosphere following the Australian New Year’s fires in 2020. The moderate HT-HH-induced enhancements in reactive chlorine seen throughout the southern middle and low-latitude stratosphere, far smaller than those in typical winter polar vortices, do not lead to appreciable chemical ozone loss; rather, extrapolar lower-stratospheric ozone remains primarily controlled by dynamical processes.

Aura Microwave Limb Sounder (MLS) measurements show that chemical processing was critical to the observed record-low Arctic stratospheric ozone in spring 2020. The 16-year MLS record indicates more denitrification and dehydration in 2019/2020 than in any Arctic winter except 2015/2016. Chlorine activation and ozone depletion began earlier than in any previously observed winter, with evidence of chemical ozone loss starting in November. Active chlorine then persisted as late into spring as it did in 2011. Empirical estimates suggest maximum chemical ozone losses near 2.8 ppmv by late March in both 2011 and 2020. However, peak chlorine activation, and thus peak ozone loss, occurred at lower altitudes in 2020 than in 2011, leading to the lowest Arctic ozone values ever observed at potential temperature levels from ~400–480 K, with similar ozone values to those in 2011 at higher levels.

Following the 15 January 2022 Hunga Tonga-Hunga Ha’apai eruption, several trace gases measured by the Aura Microwave Limb Sounder displayed anomalous stratospheric values. Trajectories and radiance simulations confirm that the H2O, SO2, and HCl enhancements were injected by the eruption. In comparison with those from previous eruptions, the SO2 and HCl injections were unexceptional, although they reached higher altitudes. In contrast, the H2O injection was unprecedented in both magnitude (far exceeding any previous values in the 17-year MLS record) and altitude (penetrating into the mesosphere). We estimate the mass of H2O injected into the stratosphere to be 146+-5 Tg - ~10% of the stratospheric burden. It may take several years for the H2O plume to dissipate. This eruption could impact climate not through surface cooling due to sulfate aerosols, but rather through surface warming due to the radiative forcing from the excess stratospheric H2O.

The exceptionally strong and long-lived Arctic stratospheric polar vortex in 2019/2020 resulted in large transport anomalies throughout the fall-winter-spring period from vortex development to breakup. These anomalies are studied using Aura MLS long-lived trace gas data for N2O, H2O,and CO, ACE-FTS CH4 , and meteorological and trace gas fields from reanalyses. Strongest anomalies are seen throughout the winter in the lower through middle stratosphere (from about 500K through 700K), with record low (high) departures from climatology in N2O and CH4 (H2O). CO also shows extreme high anomalies in midwinter through spring down to about 550K. Examination of descent rates, vortex confinement, and trace gas distributions in the preceding months indicates that the early-winter anomalies in N2O and H2O arose primarily from entrainment of air with already-anomalous values (which likely resulted from transport linked to an early January sudden stratospheric warming the previous winter during a favorable quasi-biennial oscillation phase) into the vortex as it developed in fall 2019 followed by descent of those anomalies to lower levels within the vortex. Trace gas anomalies in midwinter through the late vortex breakup in spring 2020 arose primarily from inhibition of mixing between vortex and extravortex air because of the exceptionally strong and persistent vortex. Persistent strong N2O and H2O gradients across the vortex edge demonstrate that air within the vortex and its remnants remained very strongly confined through late April (mid-May) in the middle (lower) stratosphere.

A moments/area study of meteorological reanalyses (focusing on MERRA-2, ERA-Interim, and JRA-55) allows a novel investigation of the climatology of and interannual variability and trends in the Asian summer monsoon anticyclone (ASMA). The climatological ASMA is nearly elliptical, with its major axis aligned along its centroid latitude and an aspect ratio of ∼5–8. The ASMA centroid shifts northward with height, northward and westward during development, and in the opposite direction as it weakens. ASMA position and seasonal evolution generally agree among the reanalyses, except that MERRA-2 shows over 40% larger area at 350 K. No evidence of climatological bimodality is seen in the ASMA, consistent with previous studies using modern reanalyses. ASMA moments trends are mostly neither statistically significant nor consistent among reanalyses, but area and duration increase significantly over 1979–2018, and over 1958–2018 in JRA-55; JRA-55 trends are largest for 1979–2018, suggesting that reanalysis trends may have accelerated in recent decades. ASMA centroid latitude is significantly negatively (positively) correlated with subtropical jet core latitude (altitude), and significantly negatively correlated with concurrent ENSO. Other ASMA moments and area are not strongly correlated with concurrent ENSO, but ASMA area is significantly positively correlated with ENSO two months previously. Significant (negative) correlations of ASMA area with QBO are seen only during June at 370, 390, and 410 K. These results provide a unique and comprehensive view of the structure and evolution of the ASMA and introduce new tools that can be used to further explore ASMA characteristics and impacts.