In the northern Gulf of Mexico shelf, the Mississippi-Atchafalaya River System (MARS) impacts the carbonate system by delivering freshwater with a distinct seasonal pattern in both total alkalinity (Alk) and dissolved inorganic carbon (DIC), and promoting biologically-driven changes in DIC through nutrient inputs. However, how and to what degree these processes modulate the interannual variability in calcium carbonate solubility have been poorly documented. Here, we use an ocean-biogeochemical model to investigate the impact of MARS’s discharge and chemistry on interannual anomalies of aragonite saturation state (ΩAr). Based on model results, we show that the enhanced mixing of riverine waters with a low buffer capacity (low Alk-to-DIC ratio) during high-discharge winters promotes a significant ΩAr decline over the inner-shelf. We also show that increased nutrient runoff and vertical stratification during high-discharge summers promotes strong negative anomalies in bottom ΩAr, and less intense but significant positive anomalies in surface ΩAr. Therefore, increased MARS discharge promotes an increased frequency of suboptimal ΩAr levels for nearshore coastal calcifying species. Additional sensitivity experiments further show that reductions in the Alk-to-DIC ratio and nitrate concentration from the MARS significantly modify the simulated ΩAr spatial patterns, weakening the positive surface ΩAr anomalies during high-discharge summers or even producing negative surface ΩAr anomalies. Our findings suggest that riverine water carbonate chemistry is a main driver of interannual variability in ΩAr over river dominated ocean margins.

Recent studies have demonstrated that the difference in sea surface temperature anomalies (SSTAs) between the tropical Atlantic main development region (MDR) and the tropical Pacific (Niño 3) modulates Atlantic tropical cyclone activity. This study further explores the seasonality of Pacific and Atlantic contributions to Atlantic hurricane activity. Our analysis shows that while MDR and Niño 3 SSTAs are equally important for late-season (September-November) activity, early-season (June-August) activity is largely modulated by MDR SSTAs. This reflects the increased (reduced) variance of MDR (Niño 3) SSTAs in the early-season due to their phase locking to the seasonal cycle. Further analysis yields skillful forecasts using an MDR-Niño 3 interbasin index derived from hindcasts of the North American Multi-Model Ensemble with May initial conditions. However, the prediction skill for MDR SSTAs is lower than that of Niño 3 SSTAs, suggesting that increasing the prediction skill for MDR SSTAs is key to improving seasonal outlooks.

Ice sheet melting into the Southern Ocean can change the formation and properties of the Antarctic Bottom Water (AABW). Climate models generally mimic ice sheet melting by adding uniformly-distributed freshwater fluxes in the Southern Ocean. Uniform fluxes misrepresent the heterogeneous Antarctic ice sheet melting patterns, and could bias AABW representation in models. We use a global ocean and sea-ice model to explore whether the spatial distribution and increases in freshwater fluxes can alter AABW properties, formation, and the Antarctic sea-ice area. We find that a realistic spatially varying flux sustains AABW with higher salinities compared to simulations with uniform meltwater fluxes. Finally, we show that a ~ 20% increase in ice sheet melting can trigger AABW freshening and Antarctic sea-ice expansion rates similar to those observed in the Southern Ocean since 1980, suggesting that the increasing Antarctic meltwater discharge can drive the observed AABW freshening and the Antarctic sea-ice expansion.

Ocean acidification (OA) progression is affected by multiple factors, such as ocean warming, biological production, and runoff. Here we used an ocean-biogeochemical model to assess the impact of river runoff and climate variability on the spatiotemporal patterns of OA in the Gulf of Mexico (GoM) during 1981-2014. The model showed the expected pH and aragonite saturation state (ΩAr) decline, due to the increase in anthropogenic carbon, with trends close to values reported for the Subtropical North Atlantic. However, significant departures from the basin-averaged pattern were obtained in part of the northern GoM shelf, where pH and ΩAr increased. Model sensitivity analyses showed that OA progression was counteracted by enhanced alkalinity from the Mississippi-Atchafalaya River System. Our findings highlight that river alkalinity is a key driver of carbon system variability in river-dominated ocean margins and emphasize the need to quantify riverine chemistry to properly assess acidification in coastal waters.