Public Articles
Cardiotoxic and neurobehavioral effects of sucralose and acesulfame in Daphnia magna: toward understanding ecological impacts of artificial sweeteners
and 2 collaborators
Test parameters | Biochemical response | Behavioral response (activity) | Physiological response |
---|---|---|---|
Endpoint | AChE activity | time spent swimming and feeding | HR |
Replicates per treatment | 3 | 3 | 10 |
Replicates per control | 3 | 5 | 10 |
Individuals per replicate | 10 | 1 | 1 |
Effect of adaptive deep brain stimulation in patient with Parkinson disease: A case report
and 1 collaborator
Coculture model of a liver sinusoidal endothelial cell barrier and hepatocyte spheroids-on-chip in an advanced fluidic platform
and 8 collaborators
The influence of natural variability on extreme monsoons in Pakistan
and 11 collaborators
Formation of pure anatase TiO2 by reactive pulsed dc magnetron sputtering: method for controlling target poisoning state
and 1 collaborator
In vivo evaluation of BACtrack® Skyn™: a discrete wrist-worn transdermal alcohol monitoring device marketed to the public
AN EFFICIENT LATTICE ALGORITHM FOR THE LIBOR MARKET MODEL
Incremental Risk Charge Methodology
Abstract
A Simple and Precise Method for Pricing Convertible Bond with Credit Risk
pyisotopomer: A Python package for obtaining intramolecular isotope ratio differences from mass spectrometric analysis of nitrous oxide isotopocules
and 5 collaborators
From heteronormative to homonormative: A new perspective on the evolution of sexual behavior
Test proposal document
and 1 collaborator
Review on "Sleep paralysis and trauma, psychiatric symptoms and disorders in an adult African American population attending primary medical care." by Johnson EO, Roth T, Breslau N.
and 2 collaborators
Artificial Multisensory Neuron with Fused Haptic and Temperature Perception for Multimodal In-Sensor Computing
and 9 collaborators
2D Metal-Organic Frameworks Based Optoelectronic Neuromorphic Transistors for Human Emotion-Simulation and Neuromorphic Computing
and 6 collaborators
Supporting Information for "Spike Enabled Audio Learning in Multilevel Synaptic Memristor Array Based Spiking Neural Network"
and 4 collaborators
On the sources of systemic risk in cryptocurrency markets
Exploring historical conceptualization of AI Stable Diffusion Model with prompt engineering techniques.
Chemistry, WM Revision Notes
Polar due to O-H bond
Able to hydrogen bond
Explains why alcohols have higher MBP’s than corresponding alkanes
Also explains why alcohol and water mix
O-H bond becomes less influential in longer chains
Solubility in water decreases
Other properties more similar to those of corresponding alkanes
Primary alcohols:
-O-H carbon bonded to one other
Secondary alcohols:
-O-H carbon bonded to two others
Tertiary alcohols:
-O-H carbon bonded to three others
The O-H group is oxidised by strong oxidising agents
Acidified Potassium Dichromate(VI), K2Cr2O7
Orange dichromate ion reduced to green chromate(III) ion
Cr2O72− ⇒ Cr3+
O-H group converted to carbonyl C=O group
Will not take place if there is no hydrogen attached to the carbon
Carbonyl formed depends on reacting alcohol and conditions
Aldehyde or ketone
Safer when using volatile compounds
Prevents loss of solvent, reagent, or product
Initially oxidised to an Aldehyde
Can be further oxidised to a Carboxylic Acid
Excess oxidising agent
Under reflux
If the Aldehyde is required:
Distilled in situ
Prevents further oxidation
Excess Alcohol
No reflux
Chemistry, All Storylines
All matter was contained in a singularity
Expansion from Big Bang
Hydrogen and Helium nuclei form after 3 minutes
Electron slow enough to form atoms after 10,000 years
Universe primarily Hydrogen and Helium
Matter formed gas clouds as Universe cooled
Clouds compressed, forming plasma of ionised atoms and unbound electrons
Nuclear fusion begins, giving a star
Stellar wind drives away dust cloud, forming planets
Nuclear fusion common in centres of stars
Lighter nuclei fused together to form heavier nuclei, releasing large amounts of energy
Requires extreme temperature and pressure
Completely renewable
Layers of elements form in star, heaviest at centre
Fusion of heavy elements due to increased pressure from star
When iron nuclei in core fuse, energy is absorbed
An iron core will cause a supernova
Longer life cycle than heavier stars
Will produce energy until all hydrogen is used
Expands into red giant after all energy is used
Red giant becomes unstable and outer gases drift away
Collapses down to White Dwarf, 1% of original stars size
Physics, Electricity, 13-14
\begin{equation*} \text{Power}=\frac{\text{Energy Transferred}}{\text{Time}} \end{equation*} Power is measured in watts, and energy in joules. Alternatively, one kilowatt-hour is the energy transferred in one hour from a source of power 1000W; 3.6MJ.
Current is a flow of charge. Charge itself is a fundamental property of matter. Charge can be positive or negative, and opposite charges attract. Charge itself is measured in coulombs, with the charge on one electron being −1.6 × 10−19C.
Conduction is the flow of electric charges through a material. An insulator is a material that will not readily conduct electricity, as it has no free charges - the tightly bound electrons would require a relatively large amount of energy to be freed.
By rubbing together two insulators, electrons are transferred from one material to another, leaving neither material with a neutral charge.
Metals are good conductors due to the fact that some of their atomic electrons are free to move between atoms and carry charge.
Electrostatic phenomena are when there is no flow of continuous charge. A continuous charge is known as a current. \begin{equation*}
Q=It
\end{equation*} The direction of conventional current is from positive to negative. However electrons, being negatively charged, flow from negative to positive.
Current is the rate of flow of charge: With a current of one ampere, one coulomb will pass a given point every second.
An electric current will be set up in a conductor if there is:
An energy source, such as a battery made up of cells
A continuous circuit
Charge is conserved wiothin a circuit. At any given point, the input and output charge must be equal - Kirchoff’s First Law
In a series circuit, current is the same everywhere. In a parallel circuit, the sum of the current in branches is equal to the total current.
Chemistry, O Revision Notes
Ionic solids are held together by opposite charges
Anions and Cations form giant ionic lattice
Eg. NaCl
Each Na+ ion surrounded by six Cl− ions and vice versa
Overall attraction within lattice greater than repulsion
Strong melting and boiling points
Many ionic substances dissolve readily in water
Ions becomes surrounded by water and spread out
Ions lose regular arrangement - becomes random
Ions behave independently of each other
Not all ionic substances dissolve readily in solution, as energy changes are an important factor.
Before an ionic solid can dissolve, the ions must be separated from their lattice. Energy must be supplied to overcome the electrostatic attractions, making it an endothermic process.
ΔLEH is the enthalpy change when one mole of a solid is formed from its separated ions in their gaseous states.
Energy required to form a lattice is negative
Energy required to break a lattice is therefore −ΔLEH
Lattice enthalpy is affected by both the charge and radii of the ions.
A greater charge will increase the magnitude of the lattice enthalpy
A greater atomic radii will decrease the magnitude of the lattice enthalpy
Larger separation between charges leads to smaller attraction
The magnitude of the lattice enthalpy will increase with greater charge density
Thus, substances with large enthalpies are normally insoluble
A2 Physics, Turning Points in Physics
Stream of electrons; current
Produced in discharge tubes
Low pressure tube with a high potential difference
Hot cathode emits electrons by thermionic emission and accelerates them through gas
Gas atoms are ionised, so have a positive charge
Low pressure allows them to accelerate towards cathode with few collisions
Collision with cathode releases more electrons
Gas is therefore conducting
De-excitation of electrons in gas atoms gives off visible and UV photons
Gas at very low pressure will have fewer collisions with electrons
Cathode ray hits glass in tube, exciting glass electrons
Glass then glows due to de-excitation
The emission of electrons from a hot cathode is known as thermionic emission.
Few electrons in the lattice are delocalised throughout crystal lattice
Allow conduction
The work function gives the minimum energy to remove one of these electrons
Heating of cathode transfers energy to free electrons
Overcome attractive electrical force of lattice
Emitted from metal surface
Thermionic emission does not require a gas to be present. An electron beam will be formed in an evacuated tube as the electrons do not collide; this is the bases of a thermionic valve.
Contain an electron gun
Annular anode helps acceleration
The cathode can be heated directly or indirectly.
Direct Heating
Tungsten filament with zirconium dioxide
Zirconium Dioxide reduces work function, resulting in greater rate of electron emission
Indirect Heating
Electric filament heats a separate cathode
Made of nickel, coated in oxides of barium calcium and aluminium
Operates efficiently at lower temperatures
Work done on a charged particle accelerating between a potential difference is given by W = QV. So, for an electron, \begin{gather*} W=eV\\ \therefore E_k=eV\\ \therefore \frac{1}{2}mv^2=eV \end{gather*} This gives the definition of the electronvolt; the energy gained by an electron after it has been accelerated through a potential difference of 1V.