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Jason R. Green edited Theory.tex
over 9 years ago
Commit id: e1f82d58a4125dbb129e74c983a67faf894535a9
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\begin{equation}
k(t) = \left(\frac{dS(t)^{-1}}{dt}\right)
\end{equation}
When it comes to mixed second order reactions, the rate law does not allow a survival function to be obtained for the process because the rate law only allows the survival function of one reactant to be looked at. The rate law of a mixed second order reaction is
\begin{equation}
\int\frac{dx}{(C_A(0)]-x)(C_B(0)-x)}=k(t)
\end{equation}
Taking the time derivative of the left hand side gives
\begin{equation}
\int\frac{\frac{dx}{dt}}{{(C_A(0)-x)(C_B(0)-x)}}dt = k(t)
\end{equation}
And from that definition of k(t), again, we can arrive at the inequality.