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Jason R. Green edited Abstract.tex
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Fluctuating rate coefficients are necessary to describe disordered kinetic processes with phenomenological, mass-action rate laws. First-order rate laws for irreversible decay have been the primary focus of this approach, but kinetic processes with an overall order higher than one may also show disorder. Here we present a measure of the total disorder, static or dynamic, in irreversible decay for $A^n\to \textrm{products}$, $n=1,2,3,\ldots$.
This The measure
quantifies the cumulative deviations of the rate coefficient history
from a constant value -- we introduce is the inequality between the time-integrated square of the rate coefficient
(times (multiplied by the time interval of interest) and the square of the time-integrated rate coefficient. Applying this measure to empirical models for disordered kinetics of order $n\geq 2$ shows this inequality measures the
variation cumulative deviations in rate coefficients
from a constant value for this class of kinetic processes. The equality is a necessary and sufficient condition for the traditional kinetics with ``rate constants'' to hold.