this is for holding javascript data
Jason R. Green edited Nonlinear irreversible kinetics.tex
over 9 years ago
Commit id: c6022d0e7749d86f95b7cb798423146d857e54d2
deletions | additions
diff --git a/Nonlinear irreversible kinetics.tex b/Nonlinear irreversible kinetics.tex
index f420fab..afb8746 100644
--- a/Nonlinear irreversible kinetics.tex
+++ b/Nonlinear irreversible kinetics.tex
...
\equiv \frac{d}{dt}\frac{1}{S_i(t)^{i-1}}
= (i-1)\omega C_i(0)^{i-1}
\end{equation}
As shown in equation 4, the The statistical length $\mathcal{L}_i$ is the integral of the cumulative
time dependent time-dependent rate coefficient over a period of time
$\Delta{t}$. The $\Delta{t}$, and the divergence is the cumulative square of the rate coefficient, multiplied by the time interval. %The statistical length is
\begin{equation} %\begin{equation}
% \mathcal{L}_i(\Delta t)^2 =
\left[\int_{t_i}^{t_f}(i-1)\omega(C_i^{i-1})dt\right]^2
\end{equation}
and \left[\int_{t_i}^{t_f}(i-1)\omega C_i^{i-1}(0)\,dt\right]^2
%\end{equation}
%and the divergence is
\begin{equation} %\begin{equation}
% \frac{\mathcal{J}_i(\Delta t)}{\Delta t} =
\int_{t_i}^{t_f}{(i-1)^2\omega^2}\left(C_i^{i-1}\right)^{2} \int_{t_i}^{t_f}{(i-1)^2\omega^2}\left(C_i^{i-1}(0)\right)^{2} dt.
\end{equation}
Both %\end{equation}
For the
equations governing traditional kinetics, both the statistical length squared and the divergence are
$(i-1)^2\omega^2([A_0]^{n-1})^2\Delta $(i-1)^2\omega^2\left(C_i^{i-1}(0)\right)^2\Delta t^2$: the bound holds when there is no static or dynamic disorder, and a single rate coefficient is sufficient to characterize irreversible decay.
The nonlinearity of the rate law leads to solutions that depend on concentration. This concentration dependence is also present in both $\mathcal{J}$ and $\mathcal{L}$.