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Jason R. Green edited Abstract.tex
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Fluctuating rate coefficients are necessary in the mass-action rate laws of kinetic processes with disorder. Measuring the fluctuations of rate coefficients is a challenge, particularly for nonlinear rate laws. Here we present a measure of the total
disorder, static or dynamic, disorder in the kinetics of irreversible decay $A^i\to \textrm{products}$, $i=1,2,3,\ldots n$ governed by (non)linear rate equations. We measure the inequality between the time-integrated square of the rate coefficient (multiplied by the time interval of interest) and the square of the time-integrated rate coefficient.
By applying We apply this measure of the rate coefficient history to empirical models for
static and dynamically disordered kinetics with $i\geq 2$,
we show which shows this inequality measures the cumulative
deviations deviation in rate coefficients from a constant value. The equality is a necessary and sufficient condition for the traditional rate laws with ``rate constants'' to hold for
this class of irreversible kinetic processes.