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Jason R. Green edited $n^{th}$-order decay.tex
over 9 years ago
Commit id: c0dbcedf07f9ce45fa975c1f03e3d43e1034e9f8
deletions | additions
diff --git a/$n^{th}$-order decay.tex b/$n^{th}$-order decay.tex
index 337ae37..877e0fd 100644
--- a/$n^{th}$-order decay.tex
+++ b/$n^{th}$-order decay.tex
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\begin{equation}
k_n(t) \equiv (\frac{d\frac{1}{(S(t)^{n-1)}}}{dt})\equiv(n-1)\omega[A_0]^{n-1}
\end{equation}
The nonlinearity of the rate law leads to solutions that depend on concentration. As shown in equation 4, the statistical length is the integral of the cumulative time dependent rate coefficient over a period of time $\Delta{t}$. The statistical length is
\begin{equation}
\mathcal{L}_n(\Delta t)^2 = \left[\int_{t_i}^{t_f}(n-1)\omega([A_0]^{n-1})dt\right]^2
\end{equation}