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Jonathan Nichols edited $n^{th}$ Order Irreversible Decay.tex
over 9 years ago
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\end{equation}
The time dependent rate coefficient is
\begin{equation}
k(t)\equiv(\frac{d\frac{1}{(S(t)^\expn{n-1)}}}{dt})\equiv(n-1)\omega[A_0]^{n-1} k(t)\equiv(\frac{d\frac{1}{(S(t)^{n-1)}}}{dt})\equiv(n-1)\omega[A_0]^{n-1}
\end{equation}
As shown in equation 4, the statistical length is the integral of the cumulative time dependent rate coefficient over a period of time $\Delta{t}$. The statistical length is
\begin{equation}
\mathcal{L}(\Delta
t)^2=\left[\int_{t_i}^{t_f}\sqrt{(n-1)\omega([A]_0^\expn{n-1})}dt\right]^2 t)^2=\left[\int_{t_i}^{t_f}\sqrt{(n-1)\omega([A]_0^{n-1})}dt\right]^2
\end{equation}
Following length, the Fisher divergence is the integral of the cumulative time dependent rate coefficient squared over a period of time $\Delta{t}$. The Fisher divergence is
\begin{equation}
\frac{\mathcal{J}( \Delta t)}{\Delta
t}=\int_{t_i}^{t_f}{(n-1)^2\omega^2}([A_0]^\expn{n-1})^\expn{2}}} t}=\int_{t_i}^{t_f}{(n-1)^2\omega^2}([A_0]^{n-1})^{2}}} dt
\end{equation}
The inequality becomes
\begin{equation}
(n-1)^2\omega^2([A_0]^\expn{n-1})^2\Delta t^2-[(n-1)\omega[A_0]^\expn{n-1}\Delta (n-1)^2\omega^2([A_0]^{n-1})^2\Delta t^2-[(n-1)\omega[A_0]^{n-1}\Delta t]^2\geq0
\end{equation}
Again, we see that when the bound
$(n-1)^2\omega^2([A_0]^\expn{n-1})^\expn{2}\Delta t^2=[(n-1)\omega[A_0]^\expn{n-1}\Delta $(n-1)^2\omega^2([A_0]^{n-1})^{2}\Delta t^2=[(n-1)\omega[A_0]^{n-1}\Delta t]^2$ holds, there is no static or dynamic disorder, and a single rate coefficient can be defined for the irreversible decay process.