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Jason R. Green edited Nonlinear irreversible kinetics.tex
over 9 years ago
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\begin{equation}
\frac{dC_i(t)}{dt} = k_i(t)\left[C_i(t)\right]^i.
\end{equation}
Experimental data
corresponds is typically a concentration profile corresponding to the integrated form of the rate
law, a concentration profile. law. For example, in the case of the $i^{th}$-order reaction, the traditional integrated rate law and a rate ``constant'', $k_i(t)\to\omega$, is
\begin{equation}
\frac{1}{C_i(t)^{i-1}} = \frac{1}{C_i(0)^{i-1}}+(i-1)\omega t.
\end{equation}
...
\begin{equation}
S_i(t) = \frac{C_i(t)}{C_i(0)} = \sqrt[i-1]{\frac{1}{1+(i-1)\omega tC_i(0)^{i-1}}},
\end{equation}
which we will use as the input to our theory.
From the survival function, Namely, we define the
time-dependent effective rate
coefficient coefficient, $k_i(t)$, through an appropriate time derivative
depending of the survival function that depends on the
total order
$i$ of reaction
\begin{equation}
k_i(t) \equiv
\begin{cases}