PL2

  • Wool and sink were known to polymers with the \(-CONH-\) peptide linkage

  • Experiments with amines and carboxylic acids led to discovery of Nylon

  • Reaction of diamines and dicarboxylic acids formed a polymer chain

Aramids

  • Research aimed at finding a strong, heat resistant fibre

  • Aromatic polyamides seemed to be good candidates

    • Rigid polymer chain

    • High ratio of carbon to hydrogen would need alot of oxygen to ignite

  • Kevlar is an aramid fibre

    • Fire resistant, very strong, and flexible

    • Low density due to atoms it is composed of

    • Rigid linear molecules line up in parallel, bonded with hydrogen bonds

      • *

        Gives rise to sheets of molecules

      • *

        Sheets will stack around a fibre to give an almost perfect structure