DF4

Bond Enthalpies

  • A chemical bond is an electrical attraction between atoms or ions

  • To break the bond completely, the atoms or ions need to theoretically be an infinite distance apart

  • The quantity of energy required to break a particular bond in a molecule is the bond enthalpy

  • The stronger the bond, the more energy required to break it, so higher bond enthalpy

  • Bond-breaking is always endothermic

  • Bond-making is always exothermic

Bond enthalpy and length

  • Shorter bonds are stronger

  • Bonds have a balance of repulsive of attractive and repulsive forces

  • Double or triple bonds are stronger as there are more electrons attracted to nuclei

  • Bond enthalpies are typically an average

    • Depends on the individual compound

Breaking bonds in a chemical reaction

  • Many reactions need heating to start

  • Initial energy required to stretch and break bonds

  • Subsequent exothermic bond-making sustains reaction

\[\textup{enthalpy change}=\sum \textup{bonds broken} - \sum \textup{bonds formed}\]