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Z Hoyt edited section_Introduction_The_need_for__.tex
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\section{Introduction}
The need for alternative foam products has become a priority in several fronts; foams are
present in two main areas, food packing and insulations, with outstanding performance, low
density and high thermal insulation makes them perfect, but both applications have a very short
life cycle and then an undesirable recyclability or biodegradability.
Polyurethane (PU) is one of the most versatile and intensively used industrial materials. By the
proper selection of reactants and changing percentage of the component in the formula, the
resulting polyurethane can be elastomer, thermoplastic, thermosetting, rigid and flexible foams.
Rigid polyurethane foams can be used as construction materials, such as polymeric concrete
...
bio-based polyols have been developed from vegetable oils such as soybean oil, canola oil, palm
oil and castor oil, due to the environmental and sustainable issues in recent years [1-5]. Developing
bio-renewable feedstock for industry is crucial now for both the economic and environmental
reasons.
Soybean oil is an annually renewable natural resource for the polyols and is available in large
quantities. For each pound of soybean oil produced, 2.67 pounds of carbon dioxide are removed
from the air [1]. Soy-based polyols can be used in various polyurethane applications by selecting
proper functional groups and side chains. Polyurethanes produced from soy-based polyols
normally exhibit equivalent or improved physical and chemical properties due to the hydrophobic
nature of triglycerides.
The selection of the Kenaf core is due to the great availability, representing more than 60% of
the Kenaf plant, and not being as desired as the fiber portion of the plant that has a higher demand,
the core also has a particular property that make it more desirable on foams, it is hydrophobic,
composites has increased the global demand for natural fiber crops. Kenaf is an annual species of
fiber crop which can grow to around 9 feet in 9 months.
When Composting PU together with other biomass waste, the biodegradation process can
happen within two weeks and the materials will be fully decomposed, having disappeared within
three to four weeks. Since the introduction of the Soy base PU, we decided to verify the industrial
compost ability of the foams and its rate. A final verification was needed to determine the degree
of toxicity in the remaining compost, Phytotoxicity, a detrimental deviation from the normal
pattern of appearance and growth of plants in response to a given substance, is designed to assess
potential effects of substances on seedling emergence and growth. As such it does not cover
chronic effects or effects on reproduction. Passing this test is without doubts a major indicator of
the compost suitability of final our product at the end of the life cycle.
The main objective of this research was to develop soy-based polyurethane foam reinforced
with Kenaf core and to investigate thermal properties, furthermore, the effect of Kenaf core
addiction when foaming the composite, the standardized compostability capacity of the foam in
the whole spectrum of samples and a final phytotoxicity test to proof a safe waste at the end of the
life cycle.
The main objective of this research was to develop soy-based polyurethane foam reinforced
with multi-walled carbon nanotubes to enhance the compressive and mechanical properties. Soy-
based polyurethane / carbon nanotubes composites with loadings of 0.5 and 1.0 wt% were
synthesized. The effects of kenaf content on the properties of soy-based polyurethane foam
composites were investigated.