When applied an electric field along the quasi-1D direction on CDW materials, nonlinear motion of CDW appears and nonlinear current and conductance can be observed \cite{Fleming_1979}. There are two problems of interest in this project. (i) What is the conductance if applied a DC electric field? (ii) What is the frequency dependence of conductance for an AC electric field?

For CDW state, the band structure breaks apart by the band gap energy \(E_g\) at the Fermi surface in the k-space since the lattice is distorted in real space with lattice constant from \(a \rightarrow 2a\). The wavelength of the potential or the CDW \(\lambda = 2a =\frac{\pi}{k_F}\) where \(k_F = \frac{\pi}{2a}\) is the Fermi wave vector. Therefore we can write the expression for the charge density as a function of position x and time t:

\[\rho(x) = \rho_0 + \rho_1 e^{i [2k_F(x-vt)+\phi]},\]

The v in the expression denotes the velocity of the right moving CDW while \(\phi\) is the phase or the translational shift in x. And the distortion potential:

\[V(x) = V_0 cos(2k_{F}r+\phi)\]

Since the charge density is dictated by potential in the absence of electric fields, thermal fluctuations and scattering events, the CDW is “pinned” on the potential. When applied an oscillating electric field with frequency \(\omega\),

\[E(t) = E_{dc} + E_{ac} cos(\omega t)\]

there will be DC and AC current contributions. The empirical DC conductance (\(E_{ac} = 0\)) is of the form\cite{Bardeen_1979}:

\[\sigma(E) = \sigma_a + \sigma_b exp(-E_0/E)\]

From previous work, CDW was modeled as a classical particle moving in a “wash board” potential, which was approximated by parabolic and sinusoidal potentials. The particle is overdamped and subjected to electric force \(e E\). Only when the applied DC electric field exceeds some threshold value \(E_{th}\) will the CDW “particle” start to “slide”, also known as the “depinning” process of CDW \cite{Gr_ner_1981}. Once depinned, the equation of motion for CDW particle can be written in terms of position x or the phase shift \(\phi\).

\[\frac{d^{2}\phi}{dt^{2}} + \Gamma \frac{d\phi}{dt} + 2k_F V_0 sin(2k_F \phi) =\frac{e}{m} (E_{dc} + E_{ac}cos(\omega t))\]

where \(\Gamma\) is the damping coefficient determined by experiment and m and e are the collective mass and charge of CDW respectively. DC conductance can be obtained by setting \(E_{ac} = 0\). Although there is no analytical solution to equation (5), numerical solution is available. In addition, similar approach is applied by varying \(E_{ac}\) and \(\omega\) when obtaining the equation of motion for applied AC field.

In this project, the approach of dealing with DC electric field is to consider the tunneling of CDW when interacting with distorted lattice potentials, which produce a band gap at the Fermi surface. When applied an electric field, the electrons in the lower band can tunnel through the gap to the conducting band, contributing to the conductance. It is clear that the larger the applied field, the more likely electrons in CDW will tunnel through the gap, which is the analogy of Zener diode \cite{Zener_1934}. The tunneling probability can be expressed as

\[P \approx exp(-E_0/E)\]

Where \(E_0\) is the function of the gap energy. The probability comes in the right hand side of equation (5), reducing the force felt by CDW by a fraction of \(P\).

\[\frac{d^{2}\phi}{dt^{2}} + \Gamma \frac{d\phi}{dt} + 2k_F V_0 sin(2k_F \phi) =\frac{e}{m} E_{dc} exp(-E_0/E_{dc})\]

The weak electric field, i.e. \(E_0 >> E_{dc}\), leads to vanishing of the force. Thus the conductance is negligible. For large field \(E_{dc} >> E_0\), the force is nonlinearly dependent upon \(E_{dc}\), thus the second term in equation (4) shows up. Moreover, the different lattice spacing gives rise to different values of gap energy. The constant in the exponent, \(E_0\), depends upon the gap energy; therefore, the relationship between the lattice spacing and the threshold electric field will also be investigated.

Secondly, this project will investigate the relationship between the AC conductance and the frequency of the applied field. This problem was approached by considering the classical single particle model in oscillation mode instead of sliding mode. For very high or very low frequency, the AC conductance vanishes since CDW is overdamped. The AC conductance plays an important role if the frequency is close to the frequency of CDW, \(\omega_0\). In this case from equation (1)

\[\omega_0 = 2k_F v\]

The resonance of the applied AC field and CDW occurs at \(\omega \approx \omega_0\), where the electric field shifts CDW by one distorted lattice spacing within one period. The resonance frequency is determined by the gap energy and also the period of the potential. This primitive result for AC conductance is shown in (Fig.2).