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\section{Exhibits}:  1) TlCsCl3  Qualitive idea. Immidate BaBiO3 in a different region In the following, we describe four examples  of periodic table using other elements that disproportionate. Correlations enhance electron phonon coupling.  a) Parent compound . Gap, requires GW. ( LDA fails ) .  b) Checked some Local stability . compute phonos  [ global stability not done ]  c) reaction path as a slice design  of a convex hull  Outcome new material, undopable. Is it realted to the large heat correlated materials, spanning functional areas  of formation ? self localization – disorder ? charge-order, superconductivity and magnetism.