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Paul Dennis edited discussion_fluids2.tex
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At a temperature of 100$^{\circ}$C a pore fluid in equilibrium with the shale has a $\delta$^{18}O value of $\approx$5‰_{VSMOW}.
We are reassured that the derived fluid $\delta$^{18}O values are consistent with our understanding of the isotopic compositions of naturally occurring fluids and suggests that the clumped isotope temperatures are robust. For example were the calcite temperatures to have been as high as the maximum reported fluid inclusion homogenization temperatures of 240$^{\circ}$C then the derived fluid $\delta$^{18}O values would need to have been in excess of 18 - 20‰_{VSMOW}. Such values are in excess of any reported data for modern geothermal and formation waters \citep{Sheppard:1986ta}.