2.4. Proof-of-Concept n-Type Si Solar Cells.
To demonstrate the effect of the SrF2/Al
electron-selective on silicon solar cells’ performance, The authors
successfully produced a series of proof-of-concept c-Si solar cells on
the n-type substrates with the partial area rear SrF2/Al
contact architecture. Figure 4A illustrates a schematic diagram of an
n-Si solar cell. To accomplish passivation and improve optical
performance, the emitter of the fabricated solar cells was coated with
an Al2O3/SiNxstack fabricated by PECVD. In Figure 4B, Vocincreases from 622 mV with Al contact directly to 645 after inserting a
2 nm SrF2 layer. Then, the Vocreaches its peak at 654 mV for the 4 nm SrF2 layer and
remains at a slight drop but still above 650 mV. The observed
improvement in the performance of the solar cell can be explained by the
decrease in recombination, which is due to the Fermi-level depinning
effect occurring at the Al/n-Si interface. 38 TheVoc of the solar cell with illumination intensity
has also been characterized to further demonstrate the removing Schottky
barrier phenomenon (Figure S1). The fill factor (FF ) and
short-circuit current (Jsc )values depict a
similar trend, as shown in figures 4C and D. The values fall as
increasing the SrF2 thickness beyond 4 nm, which is
identified with the trend with contact resistance. Figure 4E depicts the
PCE of the fabricated devices with various SrF2 layer
thicknesses.
Figure 4F compares the J-V characteristics obtained under 1 sun
illumination of both cells with and without the optimal inserting layer
SrF2 (4 nm). The PCE of the fabricated solar cell was
increased from 18.06% to 21.56%, indicating that it has the potential
to be a new potential representative DF-ECSC for dopant-free silicon
solar cells. This device has a Voc of 654 mV,Jsc of 41.91 mA·cm-2, andFF of 78.68%. Due to the low contact resistance, the FF
increased by 7.88% in comparison to the reference cell with Al contact
directly. Both Voc and Jscsaw a small performance improvement (from 622 mV, 40.98
mA·cm-2 to 654 mV, 41.91 mA·cm-2).