Prior investigations have attempted to characterize the longitudinal variability of the column number density ratio of atomic oxygen to molecular nitrogen (ΣO/N2) in the context of non-migrating tides. The retrieval of thermospheric ΣO/N2 from far ultra-violet (FUV) emissions assumes production is due to photoelectron impact excitation on O and N2. Consequently, efforts to characterize the tidal variability in O/N2 have been limited by ionospheric contamination from O+ radiative recombination at afternoon local times (LT) around the equatorial ionization anomaly. The retrieval of ΣO/N2 from FUV observations by the Ionospheric Connection Explorer (ICON) provides an opportunity to address this limitation. In this work, we derive modified ΣO/N2 datasets to delineate the response of thermospheric composition to non-migrating tides as a function of LT in the absence of ionospheric contamination. We assess estimates of the ionospheric contribution to 135.6 nm emission intensities based on either Global Ionospheric Specification (GIS) electron density, International Reference Ionosphere (IRI) model output, or observations from the Extreme Ultra-Violet imager (EUV) onboard ICON during March and September equinox conditions in 2020. Our approach accounts for any biases between the ionospheric and airglow datasets. We found that the ICON-FUV dataset, corrected for ionospheric contamination based on GIS, uncovered a previously obscured diurnal eastward wavenumber 2 tide in a longitudinal wavenumber 3 pattern at March equinox in 2020. This finding demonstrates not only the necessity of correcting for ionospheric contamination of the FUV signals but also the utility of using GIS for the correction.

Since the earliest space-based observations of Earth’s atmosphere, ultraviolet (UV) airglow has proven a useful resource for remote sensing of the ionosphere and thermosphere. The NASA Ionospheric Connection Explorer (ICON) spacecraft, whose mission is to explore the connections between ionosphere and thermosphere utilizes UV airglow in the typical way: an extreme-UV (EUV) spectrometer uses dayglow between 54 nm and 88 nm to measure the density of O+, and a far-UV spectrograph uses the O 135.6 nm doublet and N2 Lyman-Birge-Hopfield band dayglow to measure the column ratio of O to N2 in the upper thermosphere. Two EUV emission features, O+ 61.6 nm and 83.4 nm, are used for the O+ retrieval; however, many other features are captured along the EUV instrument’s spectral dimension. In this study, we examine the other dayglow features observed by ICON EUV and demonstrate that it measures a nitrogen feature around 87.8 nm which can be used to observe the neutral thermosphere.

In near-Earth space, variations in thermospheric composition have important implications for thermosphere-ionosphere coupling. The ratio of O to N2 is often measured using far-UV airglow observations. Taking such airglow observations from space, looking below the Earth’s limb allows for the total column of O and N2 in the ionosphere to be determined. While these observations have enabled many previous studies, determining the impact of non-migrating tides on thermospheric composition has proved difficult, owing to a small contamination of the signal by recombination of ionospheric O+. New ICON observations of far UV are presented here, and their general characteristics are shown. Using these, along with other observations and a global circulation model we show that under certain circumstances the impact of non-migrating tides on thermospheric composition can be observed. By comparing the amplitude of the variation seen with that in the model, both the utility of these observations and a pathway to enable future studies is shown.

Accurate photoionization rates are vital for the study and understanding of ionospheres and may account for the discrepancy in electron densities and mismatched altitude profiles of current E-region models. The underestimation of electron density profiles could be mitigated by high-resolution cross sections that preserve autoionization lines which allow solar photons to leak through to lower altitudes. We present new ionization rates calculated with high-resolution (0.001 nm) O and N2 photoionization and electron impact cross sections, and a high-resolution solar spectrum as inputs to CPI’s Atmospheric Ultraviolet Radiance Integrated Code [AURIC, Strickland et al., 1999]. The new electron impact cross sections show little structure and have minimal effect on calculations of ionization rates. Results from AURIC with updated O and N2 cross sections indicate increased production rates up to ~40% in the E-region, specifically between 100–115 km. Likewise, production rates determined using the ionospheric photoionization rate code from Meier et al. [2007] also illustrate an increase in the O and N2 production rates (typically of more than 10%) when using the newly calculated cross sections. Additionally, we find that O and N2 dominate the volume production rates above 130 km while O2 is expected to be the main contributor from 95–130 km. AURIC model results that use the default data and model results with the new O and N2 cross sections both track very well with electron density profiles determined from Arecibo ISR observations. AURIC model results using the new cross section calculations are in better agreement with Arecibo observations at higher altitudes. Our current findings indicate that O2 plays a dominant role in photoionization production rates in the E-region. Therefore it is crucial to update ab initio ionospheric models with high-resolution photoionization cross sections.

Accurate photoionization rates are vital for the study and understanding of planetary ionospheres. Previous model calculations of terrestrial photoionization rates lack sufficient spectral resolution to account for highly structured photoionization cross sections as well as the solar spectral irradiance. We present new photoionization rate calculations from CPI’s Atmospheric Ultraviolet Radiance Integrated Code [AURIC; Strickland et al., 1999] using high-resolution (0.01 Å) solar spectra and high-resolution (0.01 Å) atomic oxygen (O) and molecular nitrogen (N2) photoionization cross sections. Theoretical photoionization cross sections of O are determined utilizing the R-matrix plus pseudo-states (RMPS) approximation whereas N2 cross sections are determined using the R-matrix approximation. We include 34 high-resolution partial O state photoionization cross sections and 3 high-resolution partial N2 state photoionization cross sections with supplemental Conway [1988] tabulations for molecular oxygen and the remaining N2 states. We find that photoionization rates computed at 0.01 Å resolution differ substantially from rates computed using low-resolution cross sections, especially in the lower thermosphere below 200 km. Specifically, we find that ionization production rate ratios exhibit variations in altitude of more than ±40% between the high- and low-resolution cases. Past low-resolution calculations at various low spectral resolutions do not sufficiently account for or preserve the highly structured auto-ionization lines in the photoionization cross sections [Meier et al., 2007]. These features, in combination with high-resolution solar spectra, allow photons to penetrate deeper into the Earth’s atmosphere producing larger total ionization rates. These higher ionization rates may finally resolve data-model discrepancies in altitude profiles of electron densities due to the use of low-resolution photoionization cross sections in current E-region models.