3.1 Construction of the reaction kinetic model based on
structure-oriented lumping
According to the free radical chain reaction mechanism of delayed coking
process, 19 reaction rules were formed. Each rule included two parts:
reactant selection rule and product generation rule. Typical reaction
rules are shown in Table 3. The symbol “” means “and”; the symbol
“” means “or”.
TABLE 3 Typical reaction rules for delayed coking process