Abstract
Abstract
Electron beam synthesis of Au nanoparticles (NPs) in Si3N4/Si
thin films is studied in terms of electron irradiation in the TEM at energies
of 80, 120, 160 and 200 keV. The samples were characterized by Rutherford
Backscattering Spectrometry (RBS) and Transmission Electron Microscopy (TEM). Si3N4/Si samples
implanted with Au ions submitted to the lowest energy irradiation process show
the growth of a dense array of dm≈ 1.3 nm Au NPs within the film.
In the case of Au implanted Si3N4 samples irradiated with
electrons at 120, 160 and 200 keV, we observe a similar behavior in the growth
of NPs. The results are discussed based on irradiation induced atomic
diffusivity and sputtering arguments as well as on the energies needed to
trigger the displacement and rearrangement of atoms.