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Ruthenium-Catalysed Asymmetric Intramolecular Isomerization/Esterification Reaction: Direct Synthesis of Chiral Dihydrocoumarins
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  • Lingzi Zhao,
  • Xuchao Wang,
  • Qing Qiang,
  • Xingwei Zhao,
  • Feipeng Liu,
  • Shenci Lu,
  • Zi-Qiang Rong
Lingzi Zhao
Northwestern Polytechnical University
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Xuchao Wang
Northwestern Polytechnical University
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Qing Qiang
Northwestern Polytechnical University
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Xingwei Zhao
Northwestern Polytechnical University
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Feipeng Liu
Northwestern Polytechnical University
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Shenci Lu
Northwestern Polytechnical University
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Zi-Qiang Rong
Northwestern Polytechnical University

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Abstract

An asymmetric isomerization/intramolecular coupling reaction of allylic alcohols to synthesize chiral dihydrocoumarins was suc-cessfully accomplished through ruthenium catalysis. This method demonstrates a wide substrate applicability, excellent tolerance for various functional groups, and good enantioselectivities (up to 90% ee). It provides a convenient pathway to produce a diverse range of structurally distinct chiral dihydrocoumarins in good efficiency.
Submitted to Chinese Journal of Chemistry
26 Jan 2024Assigned to Editor
26 Jan 2024Submission Checks Completed
26 Jan 2024Review(s) Completed, Editorial Evaluation Pending
29 Jan 2024Reviewer(s) Assigned
18 Feb 2024Editorial Decision: Revise Minor