loading page

Palladium-catalyzed denitrogenative self-carbonylation of arylhydrazine using CO and O2 as an ideal oxidant
  • Yuvraj Kolekar,
  • Bhalchandra Bhanage
Yuvraj Kolekar
Institute of Chemical Technology
Author Profile
Bhalchandra Bhanage
Institute of Chemical Technology

Corresponding Author:[email protected]

Author Profile


An efficient Pd/Cu-catalyzed oxidative self-carbonylation of arylhydrazine with CO and molecular oxygen as an oxidant to afford symmetrical biaryl ketones via C-N bond activation has been developed. In this approach, arylhydrazine hydrochlorides are used as a green arylating agent which releases nitrogen and water as a byproduct. This developed protocol significantly restricts the for-mation of aryl iodide and homo-coupled azobenzene products even under favorable conditions. A library of symmetrical biaryl ke-tones with wide functionalities was synthesized in good yields under mild conditions.
28 Jun 20231st Revision Received
29 Jun 2023Submission Checks Completed
29 Jun 2023Assigned to Editor
29 Jun 2023Review(s) Completed, Editorial Evaluation Pending
30 Jun 2023Editorial Decision: Revise Minor
03 Jul 20232nd Revision Received
04 Jul 2023Submission Checks Completed
04 Jul 2023Assigned to Editor
04 Jul 2023Review(s) Completed, Editorial Evaluation Pending
04 Jul 2023Editorial Decision: Accept