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Palladium-Catalyzed Skeletal Reorganisation of Cyclobutanones Invoving Successive C−C Bond/C−H Bond Cleavage
  • Ruirui Li,
  • Xiaonan Shi,
  • Dongbing Zhao
Ruirui Li
Nankai University
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Xiaonan Shi
Nankai University
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Dongbing Zhao
Nankai University

Corresponding Author:[email protected]

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The utilization of cyclobutanones as the synthon in transition metal catalysis has been made great success. Because C(carbonyl)−C bond of cyclobutanones can be cleaved through strain release. Despite those advancements, the main catalysts in literature are Rh catalysts or Ni catalysts and the reaction with C–H bond is still underdeveloped. Herein, we realized the first palladium-catalyzed skeletal reorganisation of cyclobutanones invoving successive cleavage of C(carbonyl)−C bonds and C−H bond cleavage, which con-stitutes an rapid access to diverse indanones.
14 Feb 20231st Revision Received
16 Feb 2023Assigned to Editor
16 Feb 2023Submission Checks Completed
16 Feb 2023Review(s) Completed, Editorial Evaluation Pending
16 Feb 2023Editorial Decision: Accept