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Thermal Degradation of Glycidyl Esters in Mono- and Mono-Di-Glyceride
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  • Flemming Sparsø,
  • Thomas From,
  • Thomas Schmidt,
  • Anna Keskin,
  • Rico Bagger-Jørgensen,
  • Rasmus Miller
Flemming Sparsø
International Flavors & Fragrances Inc

Corresponding Author:[email protected]

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Thomas From
International Flavors & Fragrances Inc
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Thomas Schmidt
International Flavors & Fragrances Inc
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Anna Keskin
International Flavors & Fragrances Inc
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Rico Bagger-Jørgensen
International Flavors & Fragrances Inc
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Rasmus Miller
International Flavors & Fragrances Inc
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Abstract

Thermal treatment can be used to reduce content of glycidyl fatty acid esters (GE) in distilled monoglycerides and mono-di-glyceride products. The potential reduction of GE is temperature dependent, and low temperature (e.g. 80°C) can reduce GE to a lower level than higher temperatures. Reaching a level close to equilibrium can take weeks (at e.g. 80°), while it can be reached in hours at e.g. 150°C. The thermal treatment has, however, also negative impact on other quality parameters. The content of monoglyceride in both distilled monoglyceride and in mono-di-glycerides is also reduced during the thermal treatment. More at higher than at lower temperatures. These conclusions are built on 47 lab and pilot experiments using different mono- and mono-di-glycerides compositions (both in terms of glycerides and fatty acids), temperatures between 80°C and 200°C and starting levels of GE. A mathematical model was developed to analyse the experimental data.